Cigarette filter

ABSTRACT

An improved cigaret filter wherein dry and active green algae in the form of chlorella in a granular or powdery form which can physically trap and remove such toxic substances contained in cigaret smoke as nicotine, tar, carbon monoxide and the like and, additionally, can biologically denature and change these substances to harmless form are carried or held by a carrier comprising a fibrous, continuous-cellular formed or the like member. The filter is used as combined with a cigaret holder or directly with a cigaret. With each carrier, preferably, a total weight of 20 to 50 mg. of granular or powdery chlorella is used alone or as combined with such inorganic porous adsorbent as fine granular or powdery zeolite, silica gel, iron oxide or activated charcoal.

This invention relates to cigaret filters and, more particularly, toimprovements in the filter to be used as combined with a cigaret orcigaret holder to trap and remove toxic substances contained in smoke atthe time of smoking.

It is generally known that various substances detrimental to humanbodies such as, generally, (1) nicotine, (2) tar, (3) carbon monoxide,(4) imperfect combustion products containing carcinogenic matters, andthe like are contained in cigaret smoke. For nicotine, for example, itis said that 20 to 25 mg. of nicotine are contained usually in onecigaret and that about 3 mg. of nicotine are absorbed into the lung of asmoker in one smoking. Therefore, in order to trap such toxic substancesin smoking, there has been taken a measure wherein a filter made offibrous material of cotton, synthetic resin or glass, or made of acontinuous cellular foamed plastic or the like is used as arranged at anend of a cigaret, alone or as combined with granular or powderyactivated carbon or within a cigaret holder as combined with water withwhich the filter is impregnated. However, such filter used alone or ascombined as above is preferably of such density as will not remarkablyobstruct the flow of smoke. Therefore, there can be toxic substanceswhich are carried into the body of the smoker without contacting thefilter-forming member and any material combined with it. Further, insuch conventional measures, the trapping of toxic substances dependssolely on such physical actions as the deposition of those substances onthe filter-forming member or the like and the dissolving in theimpregnating water and, therefore, the toxic substances having passedthrough the filter are carried as they are into the human body.Particularly, it has been entirely impossible to trap carbon monoxidewhich is gaseous by means of such physical action only and, with theconventional filter, no countermeasure can be taken against thecarcinogenic matters carried into the human body through the filtermostly together with tar. The present invention has been suggested toeliminate such defects of the conventional cigaret filters.

According to the present invention, an improved cigaret filter comprisesat least dry and active green algae in a form of chlorella incorporatedin a porous columnar carrier carrying said green algae and capable oftrapping toxic substances in the cigaret smoke as deposited on thecarrier while allowing the smoke to pass therethrough, so that the toxicsubstances will contact the chlorella to be physically absorbed andtrapped in its pores and to biologically react with the chlorella so asto be denatured into harmless substances.

A primary object of the present invention is, therefore, to provide animproved cigaret filter which can act to not only physically trap butalso biologically denature toxic substances in cigaret smoke.

Other objects and advantages of the present invention will be made clearupon reading the following explanation of the invention detailed withreference to accompanying drawings, in which:

FIG. 1 is a vertically sectioned view of a combination of a generallyused cigaret holder and a cigaret filter in an aspect of the presentinvention;

FIG. 2 is a vertically sectioned view of a cigaret filter directlyassociated with a cigaret in another aspect of the present invention;

FIG. 3 is a vertically sectioned view of a cigaret filter alsoassociated with a cigaret in still another aspect of the presentinvention; and

FIG. 4 is a vertically sectioned view of a cigaret filter in a stillfurther aspect of the present invention as associated with a cigaret.

While the present invention shall be described in detail with referenceto the illustrated aspects, it should be understood that the intentionis not to limit the invention to these aspects but is to include allmodifications and equivalents arrangements possible within the scope ofappended claims.

Chlorella which has been recently extensively used to maintain orimprove the human health is a single cellular alga and typical of greenalgae or, in other term, chlorophyceae, and Chlorella pyrenoidosa,Chlorella ellipsoidea and Chlorella vulgaris are known as species of thesame genus. Particularly, about half of alga substances of chlorella ishigh quality proteins including many kinds of amino acids, enzymes andcarbohydrates. On the other hand, nicotine of the toxic substances inthe cigaret smoke is an alkaloid which is a basic vegetable substancebelonging to a nitrogenous compound and is, therefore, considered toeasily react or co-act with such various substances as proteins ofchlorella which is a nitrogenous compound. Further, tar is also acarbohydrate and can be, therefore, considered to act with suchchlorella substances. In the same manner, carbon monoxide which has notbeen able to be trapped or denatured at all in the conventional measuresby the physical depositing or dissolving action is expected to givecertain reaction or action particularly when such organic substances ofchlorella as above are heated by cigaret smoke. The so-calledcarcinogenic matters are contained mostly in tar. Therefore, it isevident that the rate of removal of the carcinogenic matters is higherwith the capacity of trapping and denaturing tar. The mechanism of thebiological action of such algae as chlorella expected to have sucheffects on the cigaret's toxic substances must be elucidated by futureinvestigations. However, the later described test results prove thatsuch action exists and has a remarkable effect of removing the toxicsubstances. The dry and active chlorella usually available in the marketis highly porous having a number of very fine pores in either case whenit is granular or powdery so that the rate of contact of it with thepassing cigaret smoke is as high as that of the conventionally usedactivated granular charcoal and its capacity of physically trapping thetoxic substances is also high. It is evident, therefore, that themultiplied action of the biologically trapping or denaturing capacityand physically trapping capacity is obtained by the green algae in theform of chlorella. In the present invention, chlorella is utilized totrap and remove the toxic substances in cigaret smoke employing aconventionally used filter means of, for example, a fibrous member orfoamed member as a carrier.

In FIG. 1 showing the case where a cigaret filter according to thepresent invention is used as combined with an ordinary cigaret holder, acigaret 1 is inserted and held at one end in a cigaret holding end 2' ofa holder 2 and an inner chamber 3 communicating respectively with saidholding end 2' and a small diameter conduit 2" at the other end as amouthpiece is charged with a filter 4 according to the presentinvention. In this case, granular or powdery green chlorella 5 issubstantially uniformly dispersed and carried within a columnar carrier6 consisting of a fibrous member of cotton, such synthetic resin asacetate or glass, or of a continuous cellular foamed plastic.

In FIG. 2 of another aspect wherein the filter 4 formed in the samemanner as in the case of FIG. 1 is associated as directly connected toone end with the cigaret 1, the filter 4 is in contact with a layer 1'of tobacco leaves forming the cigaret and is made integral with thecigaret by a winding paper of the cigaret 1 or another paper woundcontinuous to the winding paper.

In FIG. 3 showing the case where the filter 4 is associated directlywith the cigaret 1 as in the case of FIG. 2, the filter 4 of the presentinvention particularly comprises granular green chlorella 5 carried asone layer between a pair of columnar carriers 6 of the materialexplained with reference to FIG. 1. The chlorella 5 may be held betweenthe respective carriers 6 of the pair as they are or, alternatively, aswrapped columnarly to be of subsantially the same diameter as of thecarrier 6 with a thin paper or the like material high inair-permeability.

In still another aspect shown in FIG. 4, the filter 4 combined directlywith the cigaret 1 consists of the carrier 6 carrying the chlorella 5 assubstantially uniformly dispersed the same as in the case of FIGS. 1 or2 and arranged in direct contact with the tobacco leaf layer 1' andanother filter layer 6' only of a fibrous or foamed member containing nochlorella. As this layer 6' is made a mouthpiece, the chlorella will beprevented from dropping off the carrier.

In any one of the foregoing aspects, the chlorella used as carried orretained by the carrier 6 may be used independently or, alternatively,together with such inorganic adsorbent as generally used activatedcharcoal or zeolite having uniform pores and known as an adsorbent. Insuch case, the physically trapping capacity of such inorganic adsorbentwill be elevated and the effect of the biologically trapping anddenaturing actions expected mostly from such algae as chlorella will bealso increased.

In order to investigate effects of the thus obtained cigaret filter ofthe present invention in removing the toxic substances except carbonmonoxide gas, tests have been made in the following manner. Marketedplain cigaret "Peace" produced and sold by Japan Monopoly Corporationhas been used as cigarets to be tested. The cigaret is held in a cigaretholder charged with a cigaret filter according to the present inventionof the formation shown in FIGS. 1 or 2. The holder is connected at theexhausting end to a Cambridge filter holder having therein a collectingfilter which is used extensively for this kind of test. The filterholder is connected at the exhausting end to an aspirator whichutilizing, for example, a water flow. When water is passed through theaspirator and the cigaret is lighted, a negative pressure is causedwithin the aspirator, whereby the cigaret will be burned as if the sameis smoked, so that the smoke will be passed through the cigaret filterof the present invention, then led to the collecting filter having acollecting capacity of 0.1μ, and exhausted through an exhaust port ofthe aspirator. After one "Peace" cigaret is burned, the collectingfilter is taken out of the Cambridge holder, the collected substancesare separated from the collecting filer and compositions of the thusseparated substances are analyzed by a chromatography technique in aknown manner.

The cigaret filter of the present invention used in the test comprises acarrier formed of, similarly to generally used cigaret filter, acetatefibers in a columnar shape of 8×20 mm. and a mixture of 30 mg. ofgranular chlorella in dry and active form and 20 mg. of adsorbentconsisting of powdery iron oxide and granular activated charcoal whichis used usually for cigaret filters, the mixture being carried asuniformly dispersed within said carrier. Amounts of nicotine, tar and3,4-benzpyrene contained in the cigaret smoke after passing through thecigaret filter according to the present invention and collected by thecollecting filter are shown in Table 1, in which Sample 1 shows the casethat, for comparison, no cigaret filter is used, Sample 2 shows the casethat a cigaret filter of the present invention containing chlorella isused, and Sample 3 shows also the case that, for comparison, a so-calledaquafilter in which the above referred carrier containing no chlorellabut impregnated with 0.2 cc of plain water is used.

                  TABLE 1                                                         ______________________________________                                        Sample                                                                              Nicotine (mg.)                                                                             Tar (mg.) 3,4-benzpyrene (mg.)                             ______________________________________                                        1     2.180        16.5      7.6                                              2     0.430        4.3       0                                                3     0.350        13.8      7.6                                              ______________________________________                                    

(Test results by Japan Food Hygiene Association, a testing and analyzingauthority appointed by the Minister of Health and Welfare in Japan.)

3,4-benzpyren is known as the most remarkable cause of a lung canceramong some benzypyrene known as carcinogenic matters contained in tar ofcigarets. In the case of Sample 2, its detected amount is not alwaysabsolutely zero but tar is trapped so much by the cigaret filter of thepresent invention that the amount of 3,4-benzpyrene contained in the tarreduced to be of a very small amount is considered to be substantiallyequal to zero.

Now, the test results of investigating carbon monoxide gas removingcapacity of the cigaret filter of the present invention for cigarets ofdifferent brands made by means of a gas chromatography technique areshown in Table 2, in which the numerical values are CO gasconcentrations in the cigaret smoke in the case of using no cigaretfilter and in the case of passing the smoke through the cigaret filterof the present invention which is the same as used in the tests ofTable 1. The tests with the cigaret filter of the present invention weremade with respect to a plurality of cigarets of the respective brands.

                  TABLE 2                                                         ______________________________________                                                                  Using the cigaret                                                  No cigaret filter of the present                               Cigaret Brand  filter (p.p.m.)                                                                          invention (p.p.m.)                                  ______________________________________                                        PEACE (Japan)  About 1,000                                                                              200-400                                             Marlboro (U.S.A.)                                                                            About 1,000                                                                              250-400                                             M.S. (Italy)   About -400 100-200                                             ______________________________________                                    

(Test results by the Japan Food Hygiene Association.)

The concentration of the CO gas remaining in the smoke after passingthrough the cigaret filter of the present invention is seen to varydepending on the cigarets of the respective brands, because it isthought that, even if the tobacco leaves forming the cigarets of therespective brands are of the same kind and composition, when the originof the tobacco leaves of each cigaret is different, its composition willbe different. Anyhow, it is proved by the above tests that about 50 to80% CO gas is practically removed by the cigaret filter containingchlorella of the present invention.

In the above described tests, a mixed adsorbent of powdery iron oxideand granular activated charcoal is used as mixed with the granularchlorella but, other than activated charcoal and iron oxide, suchinorganic porous adsorbent as zeolite, silica gel and the like can beused. The dry and active green algae represented by chlorella may beused independently as carried by the carrier, without any inorganicadsorbent. However, in view of the effect of the multiplied action ofthe capacity of biologically denaturing the toxic substances mainly bythe algae and the capacity of physically trapping them mainly by theinorganic adsorbent, it is considered preferable to use algae togetherwith any of such adsorbents or with a proper combination of them.

While the amount of algae or a mixture of algae with an inorganicadsorbent to be used should vary between the case of repeatedly usingthe cigaret filter as combined with the cigaret holder and the case ofusing the filter only once as combined directly with the cigaret, it ispreferable to keep the total amount within the range of about 20 to 50mg. The porportion of the adsorbent to the algae is preferably madeabout 50% at most.

What is claimed is:
 1. A cigaret filter comprising .Iadd.an effectiveamount of .Iaddend.dry and active green algae in the form of chlorellaincorporated in a columnar carrier of porous material for trapping toxicsubstances in cigaret smoke while allowing said smoke to pass throughthe carrier .[., said chlorella being of an amount in the range of about20 to 50 mg. for said carrier of 8×20 mm.]..
 2. A cigaret filteraccording to claim 1 wherein said chlorella is granular.
 3. A cigaretfilter according to claim 1 wherein said chlorella is powdery.
 4. Acigaret filter according to claim 1 wherein said chlorella is heldbetween a pair of said carriers.
 5. A cigaret filter according to claim4 wherein said chlorella is enclosed with an air-permeable material. 6.A cigaret filter comprising .Iadd.an effective amount of.Iaddend.granular dry and active chlorella and a granular inorganicporous adsorbent incorporated in a columnar carrier for trapping toxicsubstances in cigaret smoke while allowing said smoke to passtherethrough .[., said chlorella being of an amount in the range ofabout 20 to 50 mg. for said carrier of 8×20 mm.]..
 7. A cigaret filteraccording to claim 6 wherein said adsorbent is at least one selectedfrom the group consisting of zeolite, silica gel, iron oxide andactivated charcoal.
 8. A cigaret filter according to claim 6 whereinsaid adsorbent is present in a quantity of no more than 50% of theamount of said chlorella. .Iadd.9. A cigaret filter according to claim1, wherein the amount of said dry and active green algae is in the rangeof about 20 to 50 mg. .Iaddend. .Iadd.10. A cigaret filter according toclaim 9, wherein said columnar carrier is about 8×20 mm. .Iaddend..Iadd.11. A cigaret filter according to claim 6, wherein the amount ofsaid granular dry and active chlorella is in the range of about 20 to 50mg. .Iaddend. .Iadd.12. A cigaret filter according to claim 11, whereinsaid columnar carrier is about 8×20 mm. .Iaddend.